In this paper we report the performances of a lithium-ion sulfur battery characterized by a polymer\udconfiguration. The cell, based on a sulfur-carbon cathode, a Li-Sn-C nanostructured anode and a\udPEO-based, polysulfide-added electrolyte, shows very good electrochemical performances in terms of\udstability and delivered capacity. The remarkable cell performances are ascribed to the mitigation of the\udcathode dissolution process due to the buffer action ensured by the polysulfide added to the polymer\udelectrolyte. This electrolyte configuration allows the achievement of a stable capacity ranging from 500 to\ud1500 mAh g-1S, depending on the cycling rate. The use of a polymer electrolyte and the replacement of the\udlithium metal with a Li-Sn-C nanostructured alloy are expected to guarantee high safety content, thus\udsuggesting the battery here studied as advanced energy storage system.
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机译:在本文中,我们报告了以聚合物\ ud构型为特征的锂离子硫电池的性能。该电池基于硫碳阴极,Li-Sn-C纳米结构阳极和基于udPEO的,添加了多硫化物的多硫化物电解质,在稳定性和输送能力方面表现出非常好的电化学性能。显着的电池性能归因于缓冲胶的溶解,这归因于通过添加到聚合物电解质中的多硫化物确保的缓冲作用。根据循环速率,这种电解质配置可实现500至1500 mAh g-1S的稳定容量。预期使用聚合物电解质和用Li-Sn-C纳米结构合金替代ud金属可以保证高安全含量,因此建议此处研究的电池为先进的储能系统。
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